Slick trick separates oil and water with 99.9 per cent purity

Mixtures of oil and water can be efficiently separated by pumping them into thin channels between semipermeable membranes, paving the way to cheaper and cleaner ways to deal with industrial waste. Experimental prototypes managed to recover both oil and water with a purity greater than 99.9 per cent.

Various methods already exist to split such mixtures into component parts, including spinning them in a centrifuge, mechanically skimming oil from the surface and splitting them with chemicals, electrical charges or semipermeable membranes, which allow some substances through, but not others. Membranes are the simplest method, but are currently imperfect, leaving behind a stubborn mix of oily water or watery oil.

Now, Hao-Cheng Yang at Zhejiang University in China and his colleagues have developed a more efficient method that uses two membranes – one hydrophobic layer that allows oil to pass, and one hydrophilic layer that allows water to pass – in order to cleanly separate both.

Yang says the idea has been tried before with less-than-impressive results. This is because as oil or water is removed from the mixture, the concentration of the components changes, making the membranes less efficient.

To overcome this, the team pumped the mixture into a thin channel between the two layers. In this confined space, droplets of oil are more likely to collide and accumulate, which means they can then be removed more efficiently by the hydrophobic membrane. This, in turn, increases the ratio of water in the mixture, creating a beneficial feedback loop that ensures both clean oil and water are removed continually.

“When we put the membranes [close] together, they will affect each other, making the process continue,” says Yang. “There’s a feedback between the two processes.”

In tests, the researchers found that total oil recovery increases from just 5 per cent to 97 per cent and water recovery increases from 19 per cent to 75 per cent as the channel width is narrowed from 125 millimetres to 4 millimetres. The purity of the recovered oil and water is more than 99.9 per cent, with only small amounts of waste left, says Yang.

The team is in talks with industry and Yang believes that the process is so simple that it could easily be scaled up to suitable levels within a few years.